Chemistry holds universe’s secrets

Chemistry holds universe’s secrets

Photo by Peter Miller (CC BY-NC-ND 2.0)

Originally published 29 January 2002

How do you make a universe?

Well, you’d start with some­thing like Tin­ker­toys. A good uni­verse con­struc­tion set, like a good kid’s toy con­struc­tion set, should have rods and con­nec­tors, in stan­dard­ized sizes, enough sizes to be ver­sa­tile, but not so many as to be unwieldy.

A good uni­verse con­struc­tion set should be easy to put togeth­er, fair­ly rigid once togeth­er, and not too hard to take apart.

And that’s just what the uni­verse is made of. God’s Tin­ker­toys — par­ti­cles and forces.

Start with a big box of pro­tons and elec­trons. The par­ti­cles are charged, plus and minus, so they grip togeth­er by an elec­tri­cal force.

One pro­ton and one elec­tron and you have a hydro­gen atom. Hydro­gen is a light, col­or­less gas that’s use­ful for fill­ing par­ty bal­loons (except we don’t have any rub­ber yet) or mak­ing stars.

A ball of hydro­gen, held togeth­er by grav­i­ty, is all you need to make a star. But it must to be a very big ball, with lots of weight crush­ing down, so that the tem­per­a­ture at the cen­ter reach­es 10 mil­lion degrees or so. Then some­thing curi­ous hap­pens. The pro­tons and elec­trons are wrenched apart. Two pro­tons snap togeth­er by anoth­er force, called the strong nuclear force. One of the pro­tons sheds its pos­i­tive charge and becomes a neu­tron (we’ll ignore the details). Then two of these pro­ton-neu­tron com­bi­na­tions snap togeth­er to make a heli­um nucleus.

Ener­gy is released, which is the source of the star’s heat and light. And you are on the way to hav­ing a nifty universe.

That’s what hap­pens at a star’s core. Pro­tons snap togeth­er into larg­er and larg­er atom­ic nuclei, occa­sion­al­ly chang­ing to neu­trons. If these nuclei can make their way to a cool­er place (as when a star blows itself apart), they can hold elec­trons and become the atoms of famil­iar elements.

And so it goes. Two pro­tons: heli­um. Three pro­tons: lithi­um. Four: beryl­li­um. Five: boron. Six: car­bon. Sev­en: nitro­gen. Eight: oxygen.

Each with a cor­re­spond­ing num­ber of neu­trons. Snap, snap, snap. Your uni­verse begins to get interesting.

For exam­ple, you can now make your par­ty bal­loons. Rub­ber is a chain of car­bon atoms, with hydro­gen atoms or car­bon-hydro­gen com­bi­na­tions hang­ing on the side. The con­cept is sim­ple. In prin­ci­ple, even a kid could snap it togeth­er, and many do in chem­istry labs with mod­el balls and sticks.

But don’t fill your bal­loons with hydro­gen. Two hydro­gen atoms react with an oxy­gen atom to make water, and they tend to do this explo­sive­ly, which may add more excite­ment to your par­ty than you want­ed. So, fill the bal­loons with heli­um, which does­n’t snap togeth­er with any­thing, and is also light enough to let the bal­loons float in air. After all, you’ve got a uni­verse in the mak­ing; you might want to celebrate.

You will have noticed that the great thing about God’s Tin­ker­toy set is that, as you snap in more pro­tons, neu­trons, and elec­trons, to make heav­ier and heav­ier ele­ments, the prop­er­ties of the ele­ments change in sur­pris­ing ways. Car­bon might man­i­fest itself as dia­mond, one of the hard­est sub­stances. Add one more pro­ton, neu­tron, and elec­tron and you have nitro­gen, a col­or­less gas that makes up 80 per­cent of the atmosphere.

Forty-sev­en nuclear pro­tons and you have sil­ver; 32 more (with a cor­re­spond­ing fist­ful of neu­trons) and you’ve got gold. Some Tin­ker­toy set! The sur­pris­es keep com­ing when you start con­nect­ing dif­fer­ent sorts of atoms together.

Who would guess that two col­or­less gas­es, hydro­gen and oxy­gen, togeth­er make water, the liq­uidy elixir of life?

Sol­id sodi­um, with eleven pro­tons, reacts vio­lent­ly with water.

Chlo­rine, with 17 pro­tons, is a stinky yel­low-green gas. But snap togeth­er a sodi­um atom and a chlo­rine atom and you have — voila! — salt, a tasty condi­ment for your par­ty pretzels.

You now have the mak­ings of a uni­verse (and a par­ty), and you can think about arrang­ing for some­one to come to the par­ty. All those things list­ed on the side of your break­fast food box — fats, car­bo­hy­drates, pro­teins, vit­a­mins, cal­ci­um, and iron — that build strong bod­ies, well, snap them togeth­er. There’s noth­ing in the long DNA mol­e­cule, the mas­ter plan of your body, but hydro­gen, car­bon, nitro­gen, oxy­gen, and phos­pho­rous atoms. Of course, you’ll need tens of bil­lions of those atoms to make the DNA in a sin­gle human cell.

Chem­istry has the rep­u­ta­tion for being the most bor­ing of sciences.

It’s a bum rap. Chem­istry explores the most mys­te­ri­ous secret of this amaz­ing uni­verse we live in: How, with a con­struc­tion set of a small num­ber of stan­dard­ized “knobs and sticks,” you can make stars shine, rain fall, dia­mond hard, sug­ar sweet, and give air-pow­ered gus­to to a new­born baby’s bawl. Snap. Snap, snap. Snap, snap, snap.

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