Chipping away at the iceman mystery

Chipping away at the iceman mystery

A reconstruction of how Ötzi may have appeared in life • South Tyrol Museum of Archaeology (CC BY-NC-ND 2.0)

Originally published 18 November 2003

Remem­ber the ice­man? A dozen years ago, a cou­ple of hik­ers found a mum­mi­fied body in a melt­ing glac­i­er high in the Alps, on the bor­der between Aus­tria and Italy.

The ice­man — dubbed Ötzi after the Ötz val­ley near where he was found — was about 46 years old when he died, appar­ent­ly the vic­tim of vio­lence, an arrow­head in his shoul­der. His body was quick­ly cov­ered with snow. When found, he had been entombed in ice for 5,200 years.

Ötz­i’s mum­mi­fied cadav­er offers a unique snap­shot of Late Neolith­ic-Cop­per Age life. Sci­en­tists have ana­lyzed the con­tents of Ötz­i’s stom­ach, sequenced his DNA, stud­ied his grass cloak, goatskin coat, leg­gings, belt, shoes, cap, even his underwear.

Now some incred­i­bly clever detec­tive work by an inter­na­tion­al team of sci­en­tists, led by Wolf­gang Müller of Aus­tralian Nation­al Uni­ver­si­ty in Can­ber­ra, has tracked Ötz­i’s life­long trav­els, from the place where he cut his first per­ma­nent teeth to the high alpine pass where he died.

The work is report­ed in the Octo­ber 31 [2003] issue of the jour­nal Sci­ence.

Aston­ish­ing­ly, Ötz­i’s pere­gri­na­tions are record­ed in the atoms of his body, and the clues are sort­ed out with an instru­ment called a mass spectrometer.

A “mass-spec” spe­cial­ist can tell what atom­ic ele­ments are in any sam­ple of mat­ter, and how much of each ele­ment. Iso­topes of the same ele­ment — atoms that dif­fer only by the num­ber of neu­trons in the nucle­us — can also be dis­tin­guished and counted.

Bits of Ötz­i’s tooth and thigh were sub­ject­ed to mass-spec analy­sis and made to tell their tale.

The mate­r­i­al in tooth enam­el is fixed for­ev­er at the time the tooth forms, typ­i­cal­ly at age 3 to 5, so the iso­topic com­po­si­tion of den­tal enam­el — the rel­a­tive amounts of each iso­tope of con­stituent atoms — should be iden­ti­cal to that of the food and water Ötzi con­sumed when he was a young child.

Ötz­i’s food, in turn, would bear the iso­topic sig­na­tures of the soil in which it was grown. By com­par­ing the com­po­si­tion of Ötz­i’s tooth enam­el to soils in the region of the Aus­tri­an-Ital­ian bor­der, the researchers deduced where Ötzi spent his youth: the Elsack Val­ley, about 40 miles south­east of where his body was found.

Oxy­gen atoms in Ötz­i’s teeth pro­vid­ed a con­firm­ing clue.

Oxy­gen in tooth enam­el is pri­mar­i­ly derived from ingest­ed water. There are two sta­ble iso­topes of oxy­gen, oxy­gen-16 (8 pro­tons and 8 neu­trons) and oxy­gen-18 (8 pro­tons and 10 neu­trons). Water mol­e­cules (H2O) con­tain­ing the heav­ier iso­tope of oxy­gen tend to pre­cip­i­tate more quick­ly as rain, and there­fore the ratio of oxy­gen iso­topes in ground water varies from place to place, depend­ing on weath­er pat­terns and dis­tance from the sea.

Match­ing the iso­topic com­po­si­tion of oxy­gen in Ötz­i’s teeth to present-day water sources helped the researchers pin down where Ötzi spent his youth.

Unlike tooth enam­el, the mate­r­i­al of bones is replaced in the body every 10 or 20 years. The same kind of mass-spec analy­sis with bits of Ötz­i’s thigh­bone told the researchers where he spent the last 10 or 20 years of his life, high­er in the moun­tains and miles away from the Elsack Valley.

Final­ly, the age of tiny bits of mica from food in Ötz­i’s intestines, pre­sum­ably frag­ments of the stone used to grind the grain from which the food was made, was deter­mined using radioac­tive iso­topes of argon in the mica. The age match­es that of rock just south of the place where Ötz­i’s body was found.

By count­ing atoms with a mass spec­trom­e­ter, Ötz­i’s life sto­ry unfolds, from his place of birth in the Elsack Val­ley, to his adult­hood at a high­er alpine ele­va­tion, final­ly to the snowy ridge where he met his untime­ly death.

If noth­ing else, this clever piece of work proves that Late Neolith­ic-Cop­per Age peo­ple were not nec­es­sar­i­ly home­bod­ies. Ötzi, cer­tain­ly, got around, although we may nev­er know what took him so high in the mountains.

But nev­er mind. This is one of those sci­ence sto­ries that is inter­est­ing not so much for what is done as for the fact that it can be done at all.

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